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Tae Woo Kim, In Young Kim, Tae Sung Jung, Chang Hyun Ko and Seong-Ju Hwang A New Type of Efficient CO2 Adsorbent with Improved Thermal Stability: Self-Assembled Nanohybrids with Optimized Microporosity and Gas Adsorption Functions Advanced Functional Materials 23

Version of Record online: 8 APR 2013 | DOI: 10.1002/adfm.201300071

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An effective way to synthesize efficient CO2 adsorbents from pillared materials is developed on the basis of an electrostatically derived self-assembly between exfoliated 2D nanosheets and two kinds of guest nanoclusters. The co-pillaring of basic CdO with Cr2O3 makes it possible to improve the microporosity and basicity of the resulting pore structure and to enhance the CO2 adsorption function and thermal stability of pillared materials.

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