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Haotong Wei, Hao Zhang, Gan Jin, Tianyi Na, Guoyan Zhang, Xue Zhang, Yan Wang, Haizhu Sun, Wenjing Tian and Bai Yang Coordinatable and High Charge-Carrier-Mobility Water-Soluble Conjugated Copolymers for Effective Aqueous-Processed Polymer–Nanocrystal Hybrid Solar Cells and OFET Applications Advanced Functional Materials 23

Article first published online: 15 MAR 2013 | DOI: 10.1002/adfm.201300333

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A new type of water-soluble conjugated polymer composed of poly[(3,4-dibromo-2,5-thienylene vinylene)-co-(p-phenylene-vinylene)] (PBTPV) is synthesized. Its excellent film-forming properties, stability, and photoelectric response show good potential for organic field-effect transistor and aqueous-processable hybrid solar cell applications. The carrier mobility of the aqueous PBTPV is about 5 × 10−4 cm2 V−1 s−1 and the power conversion efficiency of the water-processed PBTPV/CdTe nanocrystal hybrid photovoltaic devices reaches 3.3%.

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