E-mail a Wiley Online Library Link

Sebastian Henke, Andreas Schneemann and Roland A. Fischer Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal–Organic Frameworks Modulated by Linker Functionalization Advanced Functional Materials 23

Version of Record online: 1 JUL 2013 | DOI: 10.1002/adfm.201301256

Thumbnail image of graphical abstract

Extremely large thermal expansion is shown by pillared-layered metal–organic frameworks (MOFs) exhibiting alkoxy-functionalized 1,4-benzenedicarboxylate linkers. At a certain threshold temperature the materials reversibly switch from a narrow pore to large pore form. This unprecedented thermo-mechanical behavior is an intrinsic property of the materials and can be modulated substantially by mixing differently functionalized linkers to obtain mixed linker MOF solid solutions.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field