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Alberto V. Puga, Amparo Forneli, Hermenegildo García and Avelino Corma Production of H2 by Ethanol Photoreforming on Au/TiO2 Advanced Functional Materials 24

Version of Record online: 1 AUG 2013 | DOI: 10.1002/adfm.201301907

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Simulated solar light irradiation of ethanolic Au/TiO2 photocatalyst suspensions yields gaseous effluents of which ca. 99% is H2, produced by reduction. Minor products are hydrocarbons, CO, and CO2, whereas acetaldehyde, produced by oxidation, accumulates in the liquid phases. Production rates can be enhanced by using UV-richer light sources, up to 30 mmol gcat−1 h−1.

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