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Dandan Xu, Garrett R. Swindlehurst, Haohan Wu, David H. Olson, Xueyi Zhang and Michael Tsapatsis On the Synthesis and Adsorption Properties of Single-Unit-Cell Hierarchical Zeolites Made by Rotational Intergrowths Advanced Functional Materials 24

Article first published online: 23 SEP 2013 | DOI: 10.1002/adfm.201301975

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Self-pillared pentasil (SPP), a hierarchical zeolite, is formed by rotational intergrowth of MFI structures and MEL structures: the higher-symmetry structure (MEL, blue) serves as a connector to connect the lower-symmetry structure (MFI, red). This process is repeated over space and time, to achieve the formation of this all-crystalline hierarchical zeolite.

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