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Laure Monnereau, Martin Nieger, Thierry Muller and Stefan Bräse Tetrakis-(4-thiyphenyl)methane: Origin of a Reversible 3D-Homopolymer Advanced Functional Materials 24

Version of Record online: 17 SEP 2013 | DOI: 10.1002/adfm.201302483

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The efficient generation of a hyper-crosslinked poly(disulfide) is described. After high yielding synthesis of the monomer tetrakis-(4-thiylphenyl)methane, the polymeric material is obtained in excellent yield under mild reaction conditions. Combination of controlled de-polymerization under bio-compatible conditions and postfunctionalization gives access to the number of free termini at the surface.

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