Bin Zhou, Li-na Niu, Wei Shi, Wei Zhang, Dwayne D. Arola, Lorenzo Breschi, Jing Mao, Ji-hua Chen, David H. Pashley and Franklin R. Tay Adopting the Principles of Collagen Biomineralization for Intrafibrillar Infiltration of Yttria-Stabilized Zirconia into Three-Dimensional Collagen Scaffolds Advanced Functional Materials 24
Version of Record online: 18 NOV 2013 | DOI: 10.1002/adfm.201302920
Acac-stablized yttria-stabilized zirconia (YSZ) nano-sized precursors infuse into the fibril and coalesce in the presence of the PAH-crosslinked collagen molecules to form larger-sized precursor droplets. These precursor droplets further condense in the presence of water available within the intrafibrillar compartments of the collagen fibril into amorphous YSZ nanoparticles.
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