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Y.-G. Guo, J.-S. Lee and J. Maier AgI Nanoplates with Mesoscopic Superionic Conductivity at Room Temperature Advanced Materials 17

Version of Record online: 19 OCT 2005 | DOI: 10.1002/adma.200501215

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AgI nanoplates with unusual 7H and 9R polytype phases (see Figure) have been prepared in large quantities by a solution-based method using polyelectrolytes. The nanoplates exhibit extremely high conductivity, which is enhanced by four orders of magnitude compared to the macroscopic AgI phase (β-AgI), and a surprising conductivity isotropy, both of which can be explained by mesoscopic ionic-conductivity effects in polytype heterostructures.

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