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J. Li, J. A. Viveros, M. H. Wrue and M. Anthamatten Shape-Memory Effects in Polymer Networks Containing Reversibly Associating Side-Groups Advanced Materials 19

Version of Record online: 11 SEP 2007 | DOI: 10.1002/adma.200602260

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A new type of lightly crosslinked shape-memory polymer that contains reversibly associating side-groups is reported. H-bonding interactions stabilize mechanically strained states at low temperatures. The materials' shape recovery rate exhibits Arrhenius-like temperature dependence due to the dynamics of H-bond dissociation.

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