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F. Jiao and P. G. Bruce Mesoporous Crystalline β-MnO2—a Reversible Positive Electrode for Rechargeable Lithium Batteries Advanced Materials 19

Article first published online: 1 FEB 2007 | DOI: 10.1002/adma.200602499

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Mesoporous β-MnO2 (rutile structure) with a highly ordered pore structure (see figure) and highly crystalline walls is capable of reversibly accommodating lithium, up to a composition of Li0.92MnO2 (equivalent to a charge storage of 284 mA h g–1). Remarkably, the crystal structure and the ordered mesostructure are preserved after many cycles (Li intercalation/deintercalation).

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