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Keng-Hoong Yim, Gregory L. Whiting, Craig E. Murphy, Jonathan J. M. Halls, Jeremy H. Burroughes, Richard H. Friend and Ji-Seon Kim Controlling Electrical Properties of Conjugated Polymers via a Solution-Based p-Type Doping Advanced Materials 20

Version of Record online: 14 JUL 2008 | DOI: 10.1002/adma.200800735

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Tetrafluoro-tetracyano-quinodimethane (F4TCNQ) is used to p-dope conjugated polymers with a wide range of the HOMO levels via co-blending in a common organic solvent. Doping results in several orders of magnitude increase in the bulk conductivity and hole-current with reduced turn-on voltage. The effectiveness of doping increases as the HOMO level of the polymer becomes smaller.

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