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Chad M. Amb, Pierre M. Beaujuge and John R. Reynolds Spray-Processable Blue-to-Highly Transmissive Switching Polymer Electrochromes via the Donor–Acceptor Approach Advanced Materials 22

Version of Record online: 15 DEC 2009 | DOI: 10.1002/adma.200902917

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Spray processable blue electrochromic polymers with strictly alternating “donor-acceptor” copolymers are reported that exhibit saturated blue neutral states, highly transmissive oxidized states, excellent optical contrasts, fast switching times, and long-term redox switching stability. In addition, an alkylester-functionalized analogue is demonstrated, where the solubility of the material thin-film is irreversibly changed while allowing it to retain its electroactivity.

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