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Thomas McGlone, Carsten Streb, De-Liang Long and Leroy Cronin Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component Advanced Materials 22

Version of Record online: 8 JUN 2010 | DOI: 10.1002/adma.201001398

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Silver-Tungsten-Oxide Frameworks: Isomerically pure forms of the unique isopolyoxotungstate system are incorporated into highly connected framework materials using Ag(I) as a linking unit. Thermal treatment of the materials leads to the formation of silver microparticles embedded in a tungsten oxide matrix. This novel synthetic approach promises to create a new class of nanostructured tungsten-silver-oxides with exciting physical properties, as well as exemplifies the potential for new frameworks based upon solution processable POM clusters.

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