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Marek Sobota, Markus Happel, Max Amende, Natalia Paape, Peter Wasserscheid, Mathias Laurin and Jörg Libuda Ligand Effects in SCILL Model Systems: Site-Specific Interactions with Pt and Pd Nanoparticles Advanced Materials 23

Article first published online: 5 APR 2011 | DOI: 10.1002/adma.201004064

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Ionic liquids (ILs), such as [BMIM][Tf2N], on well-defined SCILL model catalysts are able to replace weakly adsorbed CO. On Pt, on-top CO remains adsorbed under the ionic liquid layer, but its IR signal red-shifts by over 30 cm−1. IL–adsorbate interactions are mediated by the noble metal and similar to ligands.

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