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Karl Kratz, Samy A. Madbouly, Wolfgang Wagermaier and Andreas Lendlein Temperature-Memory Polymer Networks with Crystallizable Controlling Units Advanced Materials 23

Article first published online: 4 AUG 2011 | DOI: 10.1002/adma.201102225

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The switching temperature,Tsw, which must be exceeded to initialize a shape-memory effect (SME), and Tσ,max, a temperature related to the recovery stress maximum under constant strain-activation conditions, are adjusted systematically over a wide temperature range for temperature-memory polymers. The polymers are based on crosslinked poly[ethylene-ran-(vinyl acetate)] with crystallizable controlling units and exhibit a broad melting temperature range.

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