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Lifen Xiao, Yuliang Cao, Jie Xiao, Birgit Schwenzer, Mark H. Engelhard, Laxmikant V. Saraf, Zimin Nie, Gregory J. Exarhos and Jun Liu A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium-Sulfur Batteries with Long Cycle Life Advanced Materials 24

Article first published online: 26 JAN 2012 | DOI: 10.1002/adma.201103392

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A novel vulcanized polyaniline nanotube/sulfur composite was prepared successfully via an in situ vulcanization process by heating a mixture of polyaniline nanotube and sulfur at 280 °C. The electrode could retain a discharge capacity of 837 mAh g−1 after 100 cycles at a 0.1 C rate and manifested 76% capacity retention up to 500 cycles at a 1 C rate.

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