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Omar Z. Fisher, Benjamin L. Larson, Paulina S. Hill, David Graupner, Mai-Thi Nguyen-Kim, Nermin Seda Kehr, Luisa De Cola, Robert Langer and Daniel G. Anderson Melanin-like Hydrogels Derived from Gallic Macromers Advanced Materials 24

Article first published online: 7 MAY 2012 | DOI: 10.1002/adma.201104437

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The periodate oxidation of branched poly(ethylene glycol) macromers with gallate termini results in a hydrogel with melanin-like pigmentation and quinoid electrophilicity. This electrophilicity can be exploited for facile coupling with biomolecules.

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