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Xiao-Chun Chen, Hong-Min Li, Fei Fang, Yuan-Wei Wu, Mu Wang, Guo-Bin Ma, Yu-Qiang Ma, Da-Jun Shu and Ru-Wen Peng Confinement-Induced Ordering in Dewetting and Phase Separation of Polymer Blend Films Advanced Materials 24

Version of Record online: 12 APR 2012 | DOI: 10.1002/adma.201200089

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An ordered array of droplets is self-organized and each droplet possesses a PS kernel surrounded by a PMMA rim. The formation of a regular pattern depends on the initial thickness of the polymer film and the interstitial separation of the excavated holes on the substrate; a scaling relation has been observed. This effect suggests that a low-cost and convenient approach to generate regular polymer structures over a large area can be achieved.

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