Jing Zhang, Hua Geng, Tarunpreet Singh Virk, Yan Zhao, Jiahui Tan, Chong-an Di, Wei Xu, Kamaljit Singh, Wenping Hu, Zhigang Shuai, Yunqi Liu and Daoben Zhu Sulfur-Bridged Annulene-TCNQ Co-Crystal: A Self-Assembled ‘‘Molecular Level Heterojunction’’ with Air Stable Ambipolar Charge Transport Behavior Advanced Materials 24
Article first published online: 13 APR 2012 | DOI: 10.1002/adma.201200578
An alternatively stacked donor-acceptor complex from solution is obtained. As a self-assembled “molecular level heterojunction”, this crystal displays stable ambipolar transport behaviors in ambient atmosphere. The balance hole and electron transport properties are rationalized through theoretical considerations from band structure calculation, theoretical analysis on super-exchange effects in the intermolecular electronic couplings as well as molecular reorganization energy.
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