Peter J. Skabara, Jean-Baptiste Arlin and Yves H. Geerts Close Encounters of the 3D Kind – Exploiting High Dimensionality in Molecular Semiconductors Advanced Materials 25
Charge-transport behavior in organic semiconductors is highly dependent on intermolecular orbital overlap throughout the bulk solid. The latter arises from non-covalent interactions, such as π-π or heteroatom close contacts, and can take the form of 1D, 2D or 3D assemblies. The relationship between dimensionality and charge transport properties is considered for a range of molecular-based organic semiconductors.
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