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Xiao Feng, Long Chen, Yoshihito Honsho, Oraphan Saengsawang, Lili Liu, Lu Wang, Akinori Saeki, Stephan Irle, Shu Seki, Yuping Dong and Donglin Jiang An Ambipolar Conducting Covalent Organic Framework with Self-Sorted and Periodic Electron Donor-Acceptor Ordering Advanced Materials 24

Version of Record online: 11 MAY 2012 | DOI: 10.1002/adma.201201185

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A donor-acceptor built-in covalent organic framework with segregated, periodic, and bicontinuous electron donor-acceptor ordering is reported. The framework consists of pre-organized periodic independent pathways for ambipolar electron and hole conduction and constitutes vertically ordered p-n heterojunctions with a broad D-A interface for enhanced photoconductivity.

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