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Christian Richard Parker, Zhongming Wei, Carlos R. Arroyo, Karsten Jennum, Tao Li, Marco Santella, Nicolas Bovet, Guangyao Zhao, Wenping Hu, Herre S. J. van der Zant, Marco Vanin, Gemma C. Solomon, Bo W. Laursen, Kasper Nørgaard and Mogens Brøndsted Nielsen A New Class of Extended Tetrathiafulvalene Cruciform Molecules for Molecular Electronics with Dithiafulvene-4,5-Dithiolate Anchoring Groups Advanced Materials 25

Version of Record online: 20 AUG 2012 | DOI: 10.1002/adma.201201583

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Cruciform motifs with two orthogonally oriented π-extended tetrathiafulvalenes and with differently protected thiolate end-groups are synthesized by stepwise coupling reactions. The molecules are subjected to single-molecule conductivity studies in a break-junction and to conducting probe atomic force microscopy studies in a self-assembled monolayer on gold.

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