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Cristina Cebrián, Matteo Mauro, Dimitrios Kourkoulos, Pierluigi Mercandelli, Dirk Hertel, Klaus Meerholz, Cristian A. Strassert and Luisa De Cola Luminescent Neutral Platinum Complexes Bearing an Asymmetric N^N^N Ligand for High-Performance Solution-Processed OLEDs Advanced Materials 25

Version of Record online: 13 SEP 2012 | DOI: 10.1002/adma.201202123

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The synthesis and full characterization of new platinum complexes bearing a bulky asymmetric dianionic tridentate ligand is reported. The hindrance of the ligand prevents detrimental intermolecular interactions yielding to highly emitting species in both crystalline state and thin-film. Such properties prompted their successful use in solution-processed OLEDs, showing remarkable external quantum efficiency up to 5.6%.

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