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Tian Yang, Hui Wang, Xue-Mei Ou, Chun-Sing Lee and Xiao-Hong Zhang Iodine-Doped-Poly(3,4-Ethylenedioxythiophene)-Modified Si Nanowire 1D Core-Shell Arrays as an Efficient Photocatalyst for Solar Hydrogen Generation Advanced Materials 24

Version of Record online: 7 SEP 2012 | DOI: 10.1002/adma.201202524

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A new 1D core-shell strategy is demonstrated for a hydrogen-generation photo-electrochemical cell (PEC). This Si/iodine-doped poly(3,4-ethylenedioxythiophene) (PEDOT) 1D nanocable array shows an encouraging solar-to-chemical energy-conversion efficiency. Coating with iodine-doped PEDOT can effectively enhance the photocatalytic efficiency and stability of SiNW arrays. The PEC model proposed shows a potentially promising structure for H2 production using solar energy.

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