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Ting Lei, Jin-Hu Dou and Jian Pei Influence of Alkyl Chain Branching Positions on the Hole Mobilities of Polymer Thin-Film Transistors Advanced Materials 24

Version of Record online: 24 SEP 2012 | DOI: 10.1002/adma.201202689

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Four polymers that contain alkyl chains branched at different positions on the polymer backbone are prepared. A polymer with 4-decyltetradecyl chains gives an impressive mobility of 3.62 cm2 V−1 s−1. This may arise from tighter polymer packing as well as stacking conformation change of the polymer backbone induced by the branching of the alkyl chains.

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