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Xiao-Dong Wen, Roald Hoffmann and N. W. Ashcroft Two-Dimensional CdSe Nanosheets and their Interaction with Stabilizing Ligands Advanced Materials 25

Version of Record online: 11 OCT 2012 | DOI: 10.1002/adma.201203184

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Single layer two-dimensional CdSe nanosheets are explored theoretically, highlighting the role of the coordinating (and stabilizing) ligands. Four isomeric CdSe single sheets bonded to H atoms are studied (CdSeH2), as are four similar sheets with NH3 coordinated to the Cd atoms. These are quite corrugated, unlike the pristine sheets, and have a different stability order from their graphane analogs.

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