E-mail

E-mail a Wiley Online Library Link

Lukáš Kobr, Ke Zhao, Yongqiang Shen, Richard K. Shoemaker, Charles T. Rogers and Josef Michl Inclusion Compound Based Approach to Forming Arrays of Artificial Dipolar Molecular Rotors: A Search for Optimal Rotor Structures Advanced Materials 25

Version of Record online: 8 OCT 2012 | DOI: 10.1002/adma.201203294

Thumbnail image of graphical abstract

Hexagonal tris(o-phenylenedioxy)cyclotriphosphazene (TPP) is used as ahost for organizing dipolar molecular rotor guests into regular trigonal arrays. Inclusion of molecular rotors with transversely dipolar rotators into TPP channels is followed by solid-state nuclear magnetic resonance, diifferential scanning calorimetry, X-ray diffraction, and dielectric spectroscopy. The more polar of the two rotors does not form an inclusion. The second rotor forms two different inclusions differing in crystallite size and the rotational barriers.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH