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Guksik Lee, Rebecca J. Carlton, Fumito Araoka, Nicholas L. Abbott and Hideo Takezoe Amplification of the Stereochemistry of Biomolecular Adsorbates by Deracemization of Chiral Domains in Bent-Core Liquid Crystals Advanced Materials 25

Article first published online: 26 OCT 2012 | DOI: 10.1002/adma.201203302

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Assemblies of chiral phospholipids that form spontaneously at interfaces between aqueous phases and bent-core liquid crystals can deracemize mixtures of chiral domains that otherwise form in the liquid crystal phase. An enantiomeric excess of chiral domains is induced by adsorption of either L- or D-phospholipid with the same sense of optical rotation.

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