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Tao Gong, Brian J. Adzima, Noah H. Baker and Christopher N. Bowman Photopolymerization Reactions Using the Photoinitiated Copper (I)-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) Reaction Advanced Materials 25

Article first published online: 11 FEB 2013 | DOI: 10.1002/adma.201203815

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The first bulk photopolymerization of multifunctional alkyne and azide monomers using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step-growth bulk photopolymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control.

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