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Jiye Lee, Matthew J. Bruzek, Nicholas J. Thompson, Matthew Y. Sfeir, John E. Anthony and Marc A. Baldo Singlet Exciton Fission in a Hexacene Derivative Advanced Materials 25

Version of Record online: 4 JAN 2013 | DOI: 10.1002/adma.201203982

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Hexacene, an acene with six benzene rings, is notable for its exceptionally small triplet energy, around one third of the singlet energy. Herein, singlet fission, i.e., conversion of a singlet exciton into two triplets, is demonstrated in a thin film of hexacene derivative, employing both transient absorption spectroscopy and magnetic field effects on photocurrent.

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