Christian Wäckerlin, Jan Nowakowski, Shi-Xia Liu, Michael Jaggi, Dorota Siewert, Jan Girovsky, Aneliia Shchyrba, Tatjana Hählen, Armin Kleibert, Peter M. Oppeneer, Frithjof Nolting, Silvio Decurtins, Thomas A. Jung and Nirmalya Ballav Two-Dimensional Supramolecular Electron Spin Arrays Advanced Materials 25
Article first published online: 22 JAN 2013 | DOI: 10.1002/adma.201204274
A bottom-up approach is introduced to fabricate two-dimensional self-assembled layers of molecular spin-systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH3).
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