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Danielle Schultz, Kira Gardner, Sumant S. R. Oemrawsingh, Nemanja Markešević, Kevin Olsson, Mark Debord, Dirk Bouwmeester and Elisabeth Gwinn Evidence for Rod-Shaped DNA-Stabilized Silver Nanocluster Emitters Advanced Materials 25

Article first published online: 1 FEB 2013 | DOI: 10.1002/adma.201204624

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Fluorescent DNA-stabilized silver nanoclusters contain both cationic and neutral silver atoms. The absorbance spectra of compositionally pure solutions follow the trend expected for rod-shaped silver clusters, consistent with the polarized emission measured from individual nanoclusters. The data suggest a rod-like assembly of silver atoms, with silver cations mediating attachment to the bases.

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