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Liqiang Mai, Qiulong Wei, Qinyou An, Xiaocong Tian, Yunlong Zhao, Xu Xu, Lin Xu, Liang Chang and Qingjie Zhang Nanoscroll Buffered Hybrid Nanostructural VO2 (B) Cathodes for High-Rate and Long-Life Lithium Storage Advanced Materials 25

Article first published online: 21 MAR 2013 | DOI: 10.1002/adma.201205185

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Hybrid nanostructural VO2 (B) composed of nanoscrolls, nanobelts and nanowires is synthesized through a hydrothermal-driven splitting and self-rolled method. The hybrid nanostructure with nanoscroll buffered effect provides facile strain relaxation for swelling during lithiation/delithiation, resulting in the excellent structural stability and cyclability. The interior of nanoscrolls and the interconnected voids shorten the ion diffusion pathway, which greatly enhances the rate performance.

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