Yali Luo, Buyi Li, Wei Wang, Kangbing Wu and Bien Tan Heterocyclic Microporous Polymers: Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2 Capturing Materials (Adv. Mater. 42/2012) Advanced Materials 24
On page 5703, Bien Tan and co-workers demonstrate an easy and straightforward route for the preparation of aromatic heterocycle-based microporous organic polymers. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit large CO2 adsorption capacity and high selectivity toward CO2/N2. The frontispiece shows the density map of the adsorbed CO2 molecules in the simulated microporous structure.
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