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Stefano Salvatore, Angela Demetriadou, Silvia Vignolini, Sang Soon Oh, Sebastian Wuestner, Nataliya A. Yufa, Morgan Stefik, Ulrich Wiesner, Jeremy J. Baumberg, Ortwin Hess and Ullrich Steiner Tunable 3D Extended Self-Assembled Gold Metamaterials with Enhanced Light Transmission Advanced Materials 25

Version of Record online: 3 APR 2013 | DOI: 10.1002/adma.201300193

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The optical properties of metamaterials made by block copolymer self-assembly are tuned by structural and environmental variations. The plasma frequency red-shifts with increasing lattice constant and blue-shifts as the network filling fraction increases. Infiltration with dielectric liquids leads also to a red-shift of the plasma edge. A 300 nm-thick slab of gyroid-structured gold has a remarkable transmission of 20%.

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