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Jianhua Liu, Yuan Zhang, Hung Phan, Alexander Sharenko, Preecha Moonsin, Bright Walker, Vinich Promarak and Thuc-Quyen Nguyen Effects of Stereoisomerism on the Crystallization Behavior and Optoelectrical Properties of Conjugated Molecules Advanced Materials 25

Article first published online: 11 APR 2013 | DOI: 10.1002/adma.201300255

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Three stereoisomers of DPP(TBFu)2 are separated and identified to investigate the effects of stereoisomerism on crystal structures and the optoelectrical properties. The crystal structures and FET mobility are sensitive to stereoisomers, in which the mesomer possesses the highest carrier mobility and the greatest crystallization tendency to dominate the crystallization in spin-cast films of the as-synthesized stereoisomeric mixture.

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