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Sven O. Sylvester and Jacqueline M. Cole Solar-Powered Nanomechanical Transduction from Crystalline Molecular Rotors Advanced Materials 25

Version of Record online: 18 MAR 2013 | DOI: 10.1002/adma.201300478

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A photoinduced solid-state SO2 isomerism drives a larger mechanical change (benzene-ring rotation) in a neighbouring ion (i.e., the system acts as a solar-powered molecular transducer). The ring rotation and SO2 photoisomerisation are observed using in situ X-ray crystallography and are controllable, reproducible, and metastable at low temperatures. This discovery presents a new range of materials for solar-energy-based molecular transduction.

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