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Prashant Tyagi, Irina Elena Raschip, André Deratani and Damien Quemener Reversible 2D/3D Coatings from Zipper-Assembly of Block Copolymer Micelles Advanced Materials 25

Version of Record online: 10 JUN 2013 | DOI: 10.1002/adma.201300631

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A zipper-assembly of micelles into 2D/3D coatings is reported. Block copolymer micelles that incorporate a poly(n-octadecyl methacrylate) block are zipped and unzipped on demand onto a PMMA surface. The mechanism implies an interdigitation of molecular brushes enabling 15 nm micelles to be assembled into monolayers or multilayers.

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