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Tyler K. Mullenbach, Kathryn A. McGarry, Wade A. Luhman, Christopher J. Douglas and Russell J. Holmes Connecting Molecular Structure and Exciton Diffusion Length in Rubrene Derivatives Advanced Materials 25

Version of Record online: 10 JUN 2013 | DOI: 10.1002/adma.201300641

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Connecting molecular structure and exciton diffusion length in rubrene derivatives demonstrates how the diffusion length of rubrene can be enhanced through targeted functionalization aiming to enhance self-Förster energy transfer. Functionalization adds steric bulk, forcing the molecules farther apart on average, and leading to increased photoluminescence efficiency. A diffusion length enhancement greater than 50% is realized over unsubstituted rubrene.

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