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Cheng Gu, Youchun Chen, Zhongbo Zhang, Shanfeng Xue, Shuheng Sun, Kai Zhang, Chengmei Zhong, Huanhuan Zhang, Yuyu Pan, Ying Lv, Yanqin Yang, Fenghong Li, Suobo Zhang, Fei Huang and Yuguang Ma Electrochemical Route to Fabricate Film-Like Conjugated Microporous Polymers and Application for Organic Electronics Advanced Materials 25

Version of Record online: 21 MAY 2013 | DOI: 10.1002/adma.201300839

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Film-like conjugated microporous polymers (CMPs) are fabricated by the novel strategy of carbazole-based electropolymerization. The CMP film storing a mass of counterions acting as an anode interlayer provides a significant power-conversion efficiency of 7.56% in polymer solar cells and 20.7 cd A−1 in polymer light-emitting diodes, demonstrating its universality and potential as an electrode interlayer in organic electronics.

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