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Feng Liu, Zachariah A. Page, Volodimyr V. Duzhko, Thomas P. Russell and Todd Emrick Conjugated Polymeric Zwitterions as Efficient Interlayers in Organic Solar Cells Advanced Materials 25

Version of Record online: 18 SEP 2013 | DOI: 10.1002/adma.201302477

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Conjugated polymeric zwitterions, when utilized as interlayer materials in bulk heterojunction organic solar cells, lead to significantly enhanced power conversion efficiencies. The electrostatic model of self-aligning dipolar side groups in the vicinity of the metal surface rationalizes the effects of reduced cathode work function, a key factor behind the observed enhanced efficiency.

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