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Robert M. Cook, Lara-Jane Pegg, Sophie L. Kinnear, Oliver S. Hutter, Richard J. H. Morris and Ross A. Hatton An Electrode Design Rule for Organic Photovoltaics Elucidated Using Molecular Nanolayers Advanced Energy Materials 1

Version of Record online: 8 APR 2011 | DOI: 10.1002/aenm.201100027

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The extent to which spontaneous ground-state charge transfer from the donor layer to the hole-extracting electrode in bi-layer organic photovoltaics impacts device efficiency is investigated using a pair of model high work function electrodes based on silane nanolayer derivatized indium-tin oxide glass. Silane nanolayers at this interface are also shown to be a remarkably effective means of improving the interfacial stability under constant solar illumination.

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