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Nicholas Berry, Ming Cheng, Craig L. Perkins, Moritz Limpinsel, John C. Hemminger and Matt Law Atmospheric-Pressure Chemical Vapor Deposition of Iron Pyrite Thin Films Advanced Energy Materials 2

Article first published online: 7 MAY 2012 | DOI: 10.1002/aenm.201200043

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Single-phase, large-grain, and uniform polycrystalline iron pyrite (FeS2) thin films are fabricated on glass and molybdenum-coated glass substrates by atmospheric pressure chemical vapor deposition using the reaction of iron(III) acetylacetonate and tert-butyl disulfide at 300 °C, followed by sulfur annealing at 500–550 °C to convert marcasite phase impurities to pyrite. Compositional and electrical data are presented. Pyrite is a promising candidate absorber material for earth-abundant thin-film solar cells.

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