Dr. Hongpeng Jia, Dr. Jie Ding, Prof. Andreas Hauser, Prof. Silvio Decurtins and Dr. Shi-Xia Liu Large π-Conjugated Chromophores Derived from Tetrathiafulvalene Asian Journal of Organic Chemistry 3
Make mine a large: The direct annulation of two dipyrido[3,2-a:2′,3′-c]phenazine units to a tetrathiafulvalene core leads to a large π-conjugate as a bridging ligand. Its coordination ability to transition-metal ions is exemplified by the formation of a stable dinuclear Ru2+ complex. The electrochemical, optical absorption, photoinduced intramolecular charge-transfer, and fluorescence characteristics of the ligand and the complex are described.
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