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Mikhail G. Kozlov and Sergei A. Levshakov Microwave and submillimeter molecular transitions and their dependence on fundamental constants Annalen der Physik 525

Version of Record online: 26 APR 2013 | DOI: 10.1002/andp.201300010

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Microwave and submillimeter molecular transition frequencies between nearly degenerated rotational levels, tunneling transitions, and mixed tunneling-rotational transitions show an extremely high sensitivity to the values of the fine-structure constant, α, and the electron-to-proton mass ratio, μ. This review summarizes the theoretical background on quantum-mechanical calculations of the sensitivity coefficients of such transitions to tiny changes in α and μ for a number of molecules.

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