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Priv.-Doz. Dr. Gerhard Höfle, Prof. Dr. Wolfgang Steglich and Prof. Dr. Helmut Vorbrüggen 4-Dialkylaminopyridines as Highly Active Acylation Catalysts. [New synthetic method (25)] Angewandte Chemie International Edition in English 17

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.197805691

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Activities some ten-thousand times greater than that of pyridine are found on catalysis of acylations by pyridine derivatives DMAP and PPY. The article surveys applications, e.g. in natural products chemistry, and possible explanations of this extraordinary increase in activity.

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