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Prof. Dr. Jürgen Sauer and Prof. Dr. Reiner Sustmann Mechanistic Aspects of Diels-Alder Reactions: A Critical Survey Angewandte Chemie International Edition in English 19

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.198007791

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Attempts to elucidate the mechanism of the fifty-year old classical [4 + 2]-cycloaddition reaction have been undertaken with a formidable armamentarium of methods. Paying due attention to all experimental and theoretical criteria, an attempt is made to distinguish between the mechanistic alternatives of a one-step reaction versus a two-step reaction.

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