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Prof. Dr. Wolfgang Beck, Dipl.-Chem. Wolfgang Knauer and Dr. habil. Christian Robl Synthesis and Structure of the Novel μ2-Carbido Complex [(TPP)Fe[DOUBLE BOND]C[DOUBLE BOND]Re(CO)4 Re(CO)5] Angewandte Chemie International Edition in English 29

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199003181

The title compound 2 contains an Fe[DOUBLE BOND]C[BOND]Re[BOND]Re unit. This 1,3-dimetallaallene is a novel example of the rare carbide-bridged complexes. 2 is formed on reaction of the dichlorocarbene complex 1 with pentacarbonylrhenate (TPP [DOUBLE BOND] tetra-phenylporphyrinate).

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