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Prof. Dr. Wolf-Dieter Fessner and Dipl.-Chem. Gudrun Sinerius Synthesis of Dihydroxyacetone Phosphate (and Isosteric Analogues) by Enzymatic Oxidation; Sugars from Glycerol Angewandte Chemie International Edition in English 33

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199402091

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The combination of enzymes glycerol phosphate oxidase and catalase allows the efficient preparative oxidation of glycerol phosphate 1 (X = O) with elemental oxygen which yields dihydroxyacetone phosphate 2 (X = O). Phosphate 2 can be added to various aldehydes in a one-flask, enzyme-catalyzed reaction to furnish 3 (X = O). Isosteric analogues of glycerol phosphate 1 (X = CH2, NH, S) can be converted into the corresponding adducts 3.

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