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Dr. Andreas Hirsch, Iris Lamparth and Priv.-Doz. Heinrich R. Karfunkel Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C60 and Di(ethoxycarbonyl)methylene Angewandte Chemie International Edition in English 33

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199404371

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Remarkably high selectivity marks the reaction of a regioisomeric bisadduct of C60 with defined structure to give the D3-symmetric trisadduct 1. This and other results—for example, the isolation of the seven stable isomers of C62(COOEt)4 (of the eight possible)—were obtained in the first systematic study of the regiochemistry of C60 with both experimental and theoretical methods.

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